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Publications

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2020

3.

Scarabelli, Leonardo; Sánchez-Iglesias, Ana; Pérez-Juste, Jorge; Liz-Marzán, Luis M.

A “Tips and Tricks” Practical Guide to the Synthesis of Gold Nanorods Book Chapter

In: Colloidal Synthesis of Plasmonic Nanometals, vol. 6, Chapter 21, pp. 27, Jenny Stanford Publishing, New York, 1st, 2020, ISBN: 9780429295188, (PMID: 26538043 Corresponding author).

Abstract | Links

@inbook{doi:10.1021/acs.jpclett.5b02123b,
title = {A “Tips and Tricks” Practical Guide to the Synthesis of Gold Nanorods},
author = {Leonardo Scarabelli and Ana Sánchez-Iglesias and Jorge Pérez-Juste and Luis M. Liz-Marzán},
url = {https://doi.org/10.1021/acs.jpclett.5b02123},
doi = {10.1021/acs.jpclett.5b02123},
isbn = {9780429295188},
year = {2020},
date = {2020-09-24},
urldate = {2020-09-24},
booktitle = {Colloidal Synthesis of Plasmonic Nanometals},
journal = {The Journal of Physical Chemistry Letters},
volume = {6},
pages = {27},
publisher = {Jenny Stanford Publishing},
address = {New York},
edition = {1st},
chapter = { 21},
abstract = {This chapter highlights the synthetic aspects that generally remain in the shadows in order to provide the scientific community with a user-friendly guide for the production of gold nanorods. The mechanism behind the formation of gold nanorods is still a matter of much interest because a general mechanistic model would allow us to identify specific guidelines for the design of a synthetic pathway for each nanostructure. Gold nanorod synthesis requires both thermodynamic and kinetic control, which significantly increases the number of parameters that should be taken into account. The historical turning point in the development of efficient nanorod wet synthesis methods was the introduction of the so-called seeded growth protocol, where nucleation is performed separately to prepare the seeds, which are subsequently added to the growth solution for nanorod production. The growth of gold nanorods is characterized in general by a slow kinetics, meaning that several hours are needed to complete particle growth.},
note = {PMID: 26538043
Corresponding author},
keywords = {},
pubstate = {published},
tppubtype = {inbook}
}

Close

This chapter highlights the synthetic aspects that generally remain in the shadows in order to provide the scientific community with a user-friendly guide for the production of gold nanorods. The mechanism behind the formation of gold nanorods is still a matter of much interest because a general mechanistic model would allow us to identify specific guidelines for the design of a synthetic pathway for each nanostructure. Gold nanorod synthesis requires both thermodynamic and kinetic control, which significantly increases the number of parameters that should be taken into account. The historical turning point in the development of efficient nanorod wet synthesis methods was the introduction of the so-called seeded growth protocol, where nucleation is performed separately to prepare the seeds, which are subsequently added to the growth solution for nanorod production. The growth of gold nanorods is characterized in general by a slow kinetics, meaning that several hours are needed to complete particle growth.

Close

  • https://doi.org/10.1021/acs.jpclett.5b02123
  • doi:10.1021/acs.jpclett.5b02123

Close

A “Tips and Tricks” Practical Guide to the Synthesis of Gold Nanorods
2.

Lohse, Samuel E.; Burrows, Nathan D.; Scarabelli, Leonardo; Liz-Marzán, Luis M.; Murphy, Catherine J.

Anisotropic Noble Metal Nanocrystal Growth: The Role of Halides* Book Chapter

In: Colloidal Synthesis of Plasmonic Nanometals, Chapter 15, pp. 26, Jenny Stanford Publishing, New York, 1st, 2020, ISBN: 9780429295188.

Abstract | Links

@inbook{doi:10.1021/cm402384jb,
title = {Anisotropic Noble Metal Nanocrystal Growth: The Role of Halides* },
author = {Samuel E. Lohse and Nathan D. Burrows and Leonardo Scarabelli and Luis M. Liz-Marzán and Catherine J. Murphy},
url = {https://doi.org/10.1021/cm402384j},
doi = {10.1021/cm402384j},
isbn = {9780429295188},
year = {2020},
date = {2020-09-24},
urldate = {2020-09-24},
booktitle = {Colloidal Synthesis of Plasmonic Nanometals},
journal = {Chemistry of Materials},
pages = {26},
publisher = {Jenny Stanford Publishing},
address = {New York},
edition = {1st},
chapter = {15},
abstract = {Anisotropic (nonspherical) metal nanoparticles are of widespread research interest because changing the shape of metals at the nanoscale can provide access to materials with unique optical, electronic, and catalytic properties. This chapter examines recent progress in elucidating and articulating the role halide ions play in seeded growth with particular emphasis on gold nanoparticles. It discusses the effect of halide ions on the anisotropic growth of metal nanocrystals. Although, the chapter mainly focus on gold, nanocrystals of silver, platinum, or palladium are also be included, as their formation has also been reported to be strongly influenced by halides. It reviews several examples where halides have been specifically reported to direct anisotropic growth and discusses whether the presence of halides is strictly necessary for these shapes to occur. Over the past few decades, anisotropic metal nanocrystals have been prepared by a variety of synthetic approaches, which have become increasingly convenient while providing ever more precise control over nanoparticles shape.},
keywords = {},
pubstate = {published},
tppubtype = {inbook}
}

Close

Anisotropic (nonspherical) metal nanoparticles are of widespread research interest because changing the shape of metals at the nanoscale can provide access to materials with unique optical, electronic, and catalytic properties. This chapter examines recent progress in elucidating and articulating the role halide ions play in seeded growth with particular emphasis on gold nanoparticles. It discusses the effect of halide ions on the anisotropic growth of metal nanocrystals. Although, the chapter mainly focus on gold, nanocrystals of silver, platinum, or palladium are also be included, as their formation has also been reported to be strongly influenced by halides. It reviews several examples where halides have been specifically reported to direct anisotropic growth and discusses whether the presence of halides is strictly necessary for these shapes to occur. Over the past few decades, anisotropic metal nanocrystals have been prepared by a variety of synthetic approaches, which have become increasingly convenient while providing ever more precise control over nanoparticles shape.

Close

  • https://doi.org/10.1021/cm402384j
  • doi:10.1021/cm402384j

Close

Anisotropic Noble Metal Nanocrystal Growth: The Role of Halides*
1.

Scarabelli, Leonardo; Hamon, Cyrille; Liz-Marzán, Luis M.

Design and Fabrication of Plasmonic Nanomaterials Based on Gold Nanorod Supercrystals* Book Chapter

In: Colloidal Synthesis of Plasmonic Nanometals, Chapter 22, pp. 30, Jenny Stanford Publishing, New york, 1st, 2020, ISBN: 9780429295188.

Abstract | Links

@inbook{nokey,
title = {Design and Fabrication of Plasmonic Nanomaterials Based on Gold Nanorod Supercrystals*},
author = {Leonardo Scarabelli and Cyrille Hamon and Luis M. Liz-Marzán},
doi = {https://doi.org/10.1201/9780429295188},
isbn = {9780429295188},
year = {2020},
date = {2020-09-24},
urldate = {2020-09-24},
booktitle = {Colloidal Synthesis of Plasmonic Nanometals},
pages = {30},
publisher = {Jenny Stanford Publishing},
address = {New york},
edition = {1st},
chapter = { 22},
abstract = {This chapter describes an approach toward the rational development of functional nanomaterials (or nanodevices). It focuses on a “study case” that represents a good example. The example comprises methodologies and experimental pros and cons that can be applied to other projects. Generally speaking, people can identify four distinct stages involved in the development of a nanodevice, but they are all strongly interconnected: the output of one stage is used as input for the next one. They are formulation/refining of a starting idea or hypothesis, which requires devising a specific system, fabrication of the different components and their assembly into the desired structure, systematic and detailed characterization of the produced materials, and interpretation of the experimental data on the basis of existing or new theory. These four stages can be organized in a cycle, where each “round” represents a step forward toward the design of a new functional material.},
keywords = {},
pubstate = {published},
tppubtype = {inbook}
}

Close

This chapter describes an approach toward the rational development of functional nanomaterials (or nanodevices). It focuses on a “study case” that represents a good example. The example comprises methodologies and experimental pros and cons that can be applied to other projects. Generally speaking, people can identify four distinct stages involved in the development of a nanodevice, but they are all strongly interconnected: the output of one stage is used as input for the next one. They are formulation/refining of a starting idea or hypothesis, which requires devising a specific system, fabrication of the different components and their assembly into the desired structure, systematic and detailed characterization of the produced materials, and interpretation of the experimental data on the basis of existing or new theory. These four stages can be organized in a cycle, where each “round” represents a step forward toward the design of a new functional material.

Close

  • doi:https://doi.org/10.1201/9780429295188

Close

Design and Fabrication of Plasmonic Nanomaterials Based on Gold Nanorod Supercrystals*
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